Cover Feature: <i>In Silico</i> Partial N <sub>2</sub> to NH <sub>3</sub> Conversion with a Light Atom Molecule (ChemPhysChem 6/2023)
نویسندگان
چکیده
The Cover Feature represents the concept of employing two (frustrated) Lewis acid-base pairs within a pincer-type compound to activate defiant N2-molecule; N≡N triple bond is thereby extended by remarkable 0.34 Å. Once caught tailor-made activator molecule, N2 prone stepwise reduction with hydride (compensated protons) finally release one molecule ammonia, whereas remaining nitrogen could not be fully converted NH3. More information can found in Research Article Stefan Mebs.
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ژورنال
عنوان ژورنال: ChemPhysChem
سال: 2023
ISSN: ['1439-7641', '1439-4235']
DOI: https://doi.org/10.1002/cphc.202300108